101482-10-4Relevant academic research and scientific papers
New Synthesis and Some Reactions of Vinyl Arenecarbodithioates. Wittig Reaction of (Triphenylphosphonio)methyl Arenecarbodithioate Iodides
Ishida, Masaru,Kaga, Koh-ichi,Sato, Hiroyuki,Yokoi, Masato,Kato, Shinzi
, p. 1403 - 1410 (2007/10/02)
Wittig reaction of new phosphonium salts, (triphenylphosphonio)methyl arenecarbodithioate iodides, with variety of aldehydes gave the corresponding vinyl dithiocarboxylate with nucleophiles such as potassium alkoxide or alkanethiolate was investigated and found to give the thioacylated products in high yields.Ab initio molecular orbital calculations of the model compound vinyl dithioformate, are also discussed.
Synthesis and Reactions of (Aroylthiomethyl)-triphenylphosphonium Bromides
Ishida, Masaru,Iwata, Taketoshi,Yokoi, Masato,Kaga, Kohichi,Kato, Shinzi
, p. 632 - 634 (2007/10/02)
The synthesis of (aroylthiomethyl)-triphenylphosphonium bromides and the applications as an equivalent of (mercaptomethyl)-triphenylphosphonium bromide in the synthesis of aroyl vinyl sulfides (thioenolates) are described.
