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101512-38-3

2-((3-Methylamino-propylimino)-methyl)-phenol (HL) is a tridentate Schiff base ligand that forms stable complexes with transition metals such as nickel(II) and copper(II). It has been utilized in the synthesis of polynuclear metal complexes, including dinuclear copper(II) structures with urease inhibitory activity, and serves as a co-ligand in cadmium(II) tetrazolato complexes. The ligand contributes to the formation of diverse coordination architectures, including octahedral nickel(II) complexes and azido-bridged copper(II) systems, demonstrating its versatility in coordination chemistry and potential biological applications.

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  • 101512-38-3 Structure

  • Basic information

    1. Product Name: 2-((3-methylamino-propylimino)-methyl)-phenol
    2. Synonyms: 2-((3-methylamino-propylimino)-methyl)-phenol
    3. CAS NO:101512-38-3
    4. Molecular Formula:
    5. Molecular Weight: 192.261
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 101512-38-3.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 2-((3-methylamino-propylimino)-methyl)-phenol(CAS DataBase Reference)
    10. NIST Chemistry Reference: 2-((3-methylamino-propylimino)-methyl)-phenol(101512-38-3)
    11. EPA Substance Registry System: 2-((3-methylamino-propylimino)-methyl)-phenol(101512-38-3)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 101512-38-3(Hazardous Substances Data)

101512-38-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 101512-38-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,0,1,5,1 and 2 respectively; the second part has 2 digits, 3 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 101512-38:
(8*1)+(7*0)+(6*1)+(5*5)+(4*1)+(3*2)+(2*3)+(1*8)=63
63 % 10 = 3
So 101512-38-3 is a valid CAS Registry Number.

101512-38-3Relevant articles and documents

Formation of T4(1) water tapes interconnected via centrosymmetric nickel(II) Schiff base complex to produce a 3D architecture

Bhattacharyya, Anik,Harms, Klaus,Chattopadhyay, Shouvik

, p. 12 - 17 (2014)

Addition of an aqueous methanol solution of nickel(II) acetate tetrahydrate into a methanol solution of the tridentate Schiff base, 3-(methylamino)propyliminomethylphenol (HL), resulted in the solid-state isolation of an octahedral nickel(II) complex [Ni(

Solvent-influenced syntheses and crystal structures of two azido-bridged polynuclear copper(II) complexes derived from 2-[(3-methylaminopropylimino)methyl]phenol with urease inhibitory activities

Ni, Li-Li,You, Zhong-Lu,Zhang, Lin,Wang, Che,Li, Kun

, p. 13 - 17 (2010)

An end-on azido-bridged dinuclear Cu(II) complex, [Cu2L2(μ1,1-N3)2]?CH3OH, and an end-on azido-bridged polynuclear Cu(II) complex, [CuL(μ1,1-N3)]n, derived

Formation of novel cadmium(II) tetrazolato complexes with Schiff bases as co-ligands via in situ [3+2] cyclo-addition

Bhaumik, Prasanta Kumar,Roy, Sumit,Harms, Klaus,Chattopadhyay, Shouvik

, p. 168 - 179 (2014)

Five cadmium(II) complexes, [Cd(PZTZ)2(OH2) 2] (1), [Cd2(L1)2(Cl) 2]·0.11CH3OH (2), [Cd(PRTZ)(L1)(OH 2)] (3), [Cd(PRTZ)(L2)(OH2/

Competition-driven selection in covalent dynamic networks and implementation in organic reactional selectivity

Kova?í?ek,Meister,Flídrová,Cabot,Kova?í?ková,Lehn

, p. 3215 - 3226 (2016)

Competition among reagents in dynamic combinatorial libraries of increased complexity leads to reactional self-sorting (improved regioselectivity) in mixtures of aldehydes and oligoamines. High selectivity of a given library component is transferred to a

Synthesis, crystal structure, cytotoxicity study, DNA/protein binding and molecular docking of dinuclear copper(II) complexes

Bhunia, Apurba,Mistri, Soumen,Manne, Rajesh Kumar,Santra, Manas Kumar,Manna, Subal Chandra

, p. 25 - 33 (2019)

The Schiff base 2-[(3-Methylamino-propylimino)-methyl]-phenol (HL) has been used for the synthesis of three dinuclear Cu(II) complexes, namely [Cu2L2(dca)2] (1), [Cu2L2(2,5-pdc)2]·6H2

Formation of T4(1) water tapes interconnected via centrosymmetric nickel(II) Schiff base complex to produce a 3D architecture

Bhattacharyya, Anik,Harms, Klaus,Chattopadhyay, Shouvik

, p. 12 - 17 (2014/12/10)

Addition of an aqueous methanol solution of nickel(II) acetate tetrahydrate into a methanol solution of the tridentate Schiff base, 3-(methylamino) propyliminomethylphenol (HL), resulted in the solid-state isolation of an octahedral nickel(II) complex [Ni

A rare case of solution and solid state inter-conversion of two copper(II) dimers and a copper(II) chain

Naiya, Subrata,Biswas, Saptarshi,Drew, Michael G.B.,Gomez-Garcia, Carlos J.,Ghosh, Ashutosh

experimental part, p. 26 - 33 (2011/11/30)

Three Cu(II)-azido complexes of formula [Cu2L2(N 3)2] (1), [Cu2L2(N3) 2]·H2O (2) and [CuL(N3)]n (3) have been synthesized using the sa

Carbonyl compound dependent hydrolysis of mono-condensed Schiff bases: A trinuclear Schiff base complex and a mononuclear mixed-ligand ternary complex of copper(II)

Naiya, Subrata,Sarkar, Biswarup,Song, You,Ianelli, Sandra,Drew, Michael G. B.,Ghosh, Ashutosh

experimental part, p. 2488 - 2495 (2011/01/09)

Two Schiff bases, HL1 and HL2 have been prepared by the condensation of N-methyl-l,3-propanediamine (mpn) with salicylaldehyde and 1-benzoylacetone (Hbn) respectively. HL1 on reaction with Cu(ClO 4)26

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