1015174-40-9Relevant articles and documents
Multiple aromatic amination mediated by a diiron complex
Avenier, Frederic,Goure, Eric,Dubourdeaux, Patrick,Seneque, Olivier,Oddou, Jean-Louis,Pecaut, Jacques,Chardon-Noblat, Sylvie,Deronzier, Alain,Latour, Jean-Marc
, p. 715 - 717 (2008/12/20)
(Chemical Equation Presented) Stop-frame amination: A very efficient amine transfer reaction is mediated by a biomimetic diiron complex, giving both single and double insertions of a tosylamine group into a pendant benzyl group of the ligand (see structure). The mono-insertion product has been shown by X-ray crystallography and other physical methods to be a tosylanilinato diiron(III) complex.