1015433-69-8

Basic information

• Product Name: BrH*Br^(1-)*C₁₅H₂₂N₃⁽¹⁺⁾
• CAS NO: 1015433-69-8
• Molecular Weight: 405.176
• Mol File: 1015433-69-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: BrH*Br^(1-)*C₁₅H₂₂N₃⁽¹⁺⁾(CAS DataBase Reference)
• NIST Chemistry Reference: BrH*Br^(1-)*C₁₅H₂₂N₃⁽¹⁺⁾(1015433-69-8)
• EPA Substance Registry System: BrH*Br^(1-)*C₁₅H₂₂N₃⁽¹⁺⁾(1015433-69-8)

Safety Data

• Hazardous Substances Data: 1015433-69-8(Hazardous Substances Data)

Upstream product

• 7164-98-9 1-phenylimidazole 
• 7533-40-6 (S)-2-amino-4-methylpentan-1-ol 

Relevant articles and documents

Synthesis of amidoalkyl imidazol-2-ylidene ligands and their application to enantioselective copper-catalysed conjugate addition

A small library of precursors to chiral amidoalkyl imidazol-2-ylidene ligand was synthesised via a two-step procedure starting from commercially available amino alcohols. Preliminary screening of these bidentate ligands for the enantioselective copper-catalysed conjugate addition of diethyl zinc to cyclohexenone revealed some moderate ee values. Related chiral iminoalkyl imidazole-2-ylidene ligands demonstrated much poorer enantioselectivity. The results indicate that chelation involving a covalent copper-nitrogen bond gives better selectivity than that arising from a dative copper-nitrogen co-ordination. Georg Thieme Verlag Stuttgart.