1015460-19-1Relevant articles and documents
Photocyclization of iminyl radicals: Theoretical study and photochemical aspects
Alonso, Rafael,Campos, Pedro J.,Rodriguez, Miguel A.,Sampedro, Diego
, p. 2234 - 2239 (2008)
(Graph Presented) The irradiation of acyloximes was studied by theoretical methods. CASPT2/6-31G*//CASSCF/6-31G* calculations, using an active space of 14 electrons in 11 orbitals, indicate that S2 should be the spectroscopic state, and its rel
Highly enantioselective partial hydrogenation of simple pyrroles: A facile access to chiral 1-pyrrolines
Wang, Duo-Sheng,Ye, Zhi-Shi,Chen, Qing-An,Zhou, Yong-Gui,Yu, Chang-Bin,Fan, Hong-Jun,Duan, Ying
supporting information; experimental part, p. 8866 - 8869 (2011/07/30)
A highly enantioselective Pd-catalyzed partial hydrogenation of simple 2,5-disubstituted pyrroles with a Bronsted acid as an activator has been successfully developed, providing chiral 2,5-disubstituted 1-pyrrolines with up to 92% ee.