101561-50-6

Basic information

• Product Name: 2-Methyl-3-(benzylthio)-1-propene
• Synonyms: 2-Methyl-3-(benzylthio)-1-propene;Benzylmethallyl sulfide
• CAS NO: 101561-50-6
• Molecular Formula: C₁₁H₁₄S
• Molecular Weight: 0
• Mol File: 101561-50-6.mol
• Article Data: 8

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-Methyl-3-(benzylthio)-1-propene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Methyl-3-(benzylthio)-1-propene(101561-50-6)
• EPA Substance Registry System: 2-Methyl-3-(benzylthio)-1-propene(101561-50-6)

Safety Data

• Hazardous Substances Data: 101561-50-6(Hazardous Substances Data)

Upstream product

• 100-53-8 phenylmethanethiol 
• 563-47-3 3-Chloro-2-methylpropene 
• 109-80-8 1.3-propanedithiol 
• 135472-40-1 2-benzylthio-1-bromo-2-methylpropane 
• 1458-98-6 2-methyl-3-bromo-1-propene 
• 513-42-8 3-hydroxy-2-methyl-1-propene 
• 93-68-5 3-oxo-N-o-tolylbutanamide 
• 885517-60-2 2-acetyl-3,3-bis-allylsulfanyl-N-o-tolyl-acrylamide 
• 145508-26-5 2-(bis(methylthio)methylene)-3-oxo-N-(o-tolyl)butanamide 
• 875778-80-6 2-[bis(benzylthio)methylene]-3-oxo-N-o-tolylbutanamide 
• 850998-07-1 2-acetyl-3,3-bis-ethylsulfanyl-N-o-tolyl-acrylamide 
• 135472-39-8 2-benzylthio-2-methylpropan-1-ol 
• 128800-00-0 S-Benzyl S-(2-methylallyl) dithiocarbonate 

Downstream Products

• 100-53-8 phenylmethanethiol 
• 502186-60-9 benzyl-methallyl sulfone 
• 104900-83-6 1-benzensulfonyl 2-methyl-1-propene 

Relevant articles and documents

Method of manufacturing compds. Allylnaphthol

PROBLEM TO BE SOLVED: To provide a production method of an allyl compound of carrying out the dehydration allylation of a substrate having S, C or N which is a nucleophilic atom, especially S under the presence of a catalyst system consisting of a catalyst precursor having a specific structure and a specific ligand. SOLUTION: The production method of allyl compounds comprises as follow. A catalyst precursor chosen from Formula (1) and Formula (2) and a ligand are mixed, or a catalyst precursor, an allyl alcohol, and a ligand are mixed, then allyl alcohols and a substrate are blended and made to react. The ligand is quinaldic acid or picolinic acid, and the substrate is thiols, thiocarboxylic acids or the like. [Ru(C5H5)(CH3CN)3]PF6(1). [Ru[C5(CH3)5](CH3CN)3]PF6(2). COPYRIGHT: (C)2012,JPOandINPIT

Highly efficient catalytic dehydrative S-allylation of thiols and thioic S-acids

A SH-selective allylation method using [CpRu(2-quinolinecarboxylato) (η3-C3H5)]PF6 has been realized in various solvents including aqueous media to give allyl sulfides and allyl S-thioates, demonstrating the potential applicability to lipopeptide chemistry.

REACTIONS OF PHOSPHORUS PENTACHLORIDE WITH ALLYL ARYL ETHERS, SULFIDES, AND NAPHTHALENE DERIVATIVES

Conditions for phosphorylation of allyl aryl and aryl methylallyl ethers and sulfides, as well as alkenyl- and alkoxynaphthalenes, have been developed.