101577-07-5Relevant academic research and scientific papers
Reaction of Alkynes with Iodine Monochloride Revisited
Bellina, Fabio,Colzi, Francesca,Mannina, Luisa,Rossi, Renzo,Viel, Stephane
, p. 10175 - 10177 (2003)
6-Exo-dig and/or 7-endo-dig iodocyclization reactions of functionalized acetylenic derivatives with ICl are disfavored in comparison with the corresponding electrophilic addition reactions providing regioselectively (E)-1-chloro-2-iodoethene derivatives. On the contrary, 6-endo-dig and 5-exo-dig iodocyclizations of methyl ynoates with ICl seem to be favored in comparison with the corresponding electrophilic addition reactions.
