1016571-89-3Relevant articles and documents
Phosphazene-functionalized cyclopentadienyl and its derivatives ligated rare-earth metal alkyl complexes: Synthesis, structures, and catalysis on ethylene polymerization
Jian, Zhongbao,Petrov, Alex R.,Hangaly, Noa K.,Li, Shihui,Rong, Weifeng,Mou, Zehuai,Rufanov, Konstantin A.,Harms, Klaus,Sundermeyer, Joerg,Cui, Dongmei
, p. 4267 - 4282 (2012/08/08)
Treatment of Ln(CH2SiMe3)3(thf) 2 (Ln = Sc, Y, and Lu) with 1 equiv of CpPN-type ligands C 5H4=PPh2-NH-C6H3R 2 (R = Me, L1(Me); R = s
P-Amino-cyclopentadienylidene-phosphoranes versus P-cyclopentadienyl- iminophosphoranes-tautomeric protic forms of a new bidentate CpPN ligand system
Petrov, Alex R.,Rufanov, Konstantin A.,Ziemer, Burkhard,Neubauer, Petra,Kotov, Vasily V.,Sundermeyer, Joerg
, p. 909 - 915 (2008/09/18)
The Staudinger reaction of cyclopentadienyl-phosphanes C5H 5-PMe2 (P1), C5H5-PPh2 (P2), and C5Me4H-PMe2 (P3) with azides Me 3SiN3, 1-AdN3 (Ad = 1-adamantyl) and DipN 3 (Dip = 2,6-diisopropylphenyl) has been studied. The nature of the products depends on the substituents at the C5 ring, at the phosphorus and nitrogen atoms: A series of new P-amino-cyclopentadienylidene-phosphoranes 2-6 was synthesized by reactions of P1-P3 with 1-AdN3 (2-4) and DipN 3 (5, 6). In contrast, P-cyclopentadienyl-iminophosphoranes 1 and 7 were obtained as predominant tautomers by reaction of less CH-acidic P3 with less N-basic Me3SiN3 and DipN3. Both tautomers are protonated forms of ambident, potentially chelating constrained-geometry ligands. The molecular structures of three members of this "CpPN" ligand family, 3, 4 and 6, are characterized by X-ray crystallography. The Royal Society of Chemistry.