101664-60-2Relevant academic research and scientific papers
SYNTHESIS OF ORELLANINE, THE LETHAL POISON OF A TOADSTOOL
Dehmlow, Eckehard, V.,Schulz, Hans-Joachim
, p. 4903 - 4906 (1985)
A ten step synthesis of the structure of orellanine, 3,3',4,4'- hydroxy-2,2'-bipyridyl-bis-N-oxide (1a), is described which proves the identity of the natural product.
Syntheses of Hydroxylated Bipyridines, I. - Orellanine, the Poison of a Toadstool
Dehmlow, Eckehard V.,Schulz, Hans-Joachim
, p. 857 - 862 (2007/10/02)
Two syntheses of orellanine, -3,3',4,4'-tetrol-1,1'-dioxide (5b), are developed which comprise 10 or 11 steps, respectively.The chemical reactions of 5b with diazomethane and on UV irradiation are described.
