101681-03-2

Basic information

• Product Name: 5-diphenylphosphinoyl-3-(3-phenylpropylsulfanyl)decane-2,4-diol
• CAS NO: 101681-03-2
• Molecular Weight: 524.704
• Mol File: 101681-03-2.mol

Chemical Properties

• CAS DataBase Reference: 5-diphenylphosphinoyl-3-(3-phenylpropylsulfanyl)decane-2,4-diol(CAS DataBase Reference)
• NIST Chemistry Reference: 5-diphenylphosphinoyl-3-(3-phenylpropylsulfanyl)decane-2,4-diol(101681-03-2)
• EPA Substance Registry System: 5-diphenylphosphinoyl-3-(3-phenylpropylsulfanyl)decane-2,4-diol(101681-03-2)

Safety Data

• Hazardous Substances Data: 101681-03-2(Hazardous Substances Data)

Upstream product

• 101681-06-5 1-{(2S,3S)-3-[(R)-1-(Diphenyl-phosphinoyl)-hexyl]-oxiranyl}-ethanone 
• 99381-89-2 (R)-1-{(2R,3S)-3-[(R)-1-(Diphenyl-phosphinoyl)-hexyl]-oxiranyl}-ethanol 
• 99381-89-2 (S)-1-{(2R,3S)-3-[(R)-1-(Diphenyl-phosphinoyl)-hexyl]-oxiranyl}-ethanol 
• 96302-81-7 (2RS,5RS; E)-5-diphenylphosphinoyldec-3-en-2-ol 
• 96302-81-7 (2RS,5SR; E)-5-diphenylphosphinoyldec-3-en-2-ol 
• 96302-64-6 (4RS,5SR;E)-5-diphenylphosphinoyldec-2-en-4-ol 
• 19259-70-2 n-hexyldiphenylphosphine oxide 
• 24734-68-7 3-Phenylpropane-1-thiol 
• 101681-06-5 1-{(2R,3R)-3-[(R)-1-(Diphenyl-phosphinoyl)-hexyl]-oxiranyl}-ethanone 
• 99381-89-2 (R)-1-{(2S,3R)-3-[(R)-1-(Diphenyl-phosphinoyl)-hexyl]-oxiranyl}-ethanol 
• 99381-89-2 (S)-1-{(2S,3R)-3-[(R)-1-(Diphenyl-phosphinoyl)-hexyl]-oxiranyl}-ethanol 

Downstream Products

• 101681-04-3 (2RS,3RS,E)-3-(3-phenylpropylsulfanyl)dec-4-en-2-ol 
• 101681-04-3 (2RS,3SR,Z)-3-(3-phenylpropylsulfanyl)dec-4-en-2-ol 
• 101681-08-7 (Z)-1-(3-phenylpropylsulfanyl)oct-2-ene 
• 101681-04-3 (2RS,3RS,Z)-3-(3-phenylpropylsulfanyl)dec-4-en-2-ol 

Relevant articles and documents

Control over absolute (R,S), relative (syn,anti) and geometrical (E,Z) stereochemistry in the synthesis of allylically substituted alkenes from diphenylphosphinoyl epoxy alcohols

Regioselective ring-openings of epoxy alcohols bearing a diphenylphosphinoyl (Ph2PO) group give diols which can undergo stereospecific Horner-Wittig elimination.This method was used to make allylic alcohols, unsaturated β-hydroxy sulfides, homoallylic alcohols and unsaturated amino acids, with control over their absolute (R,S), relative (syn,anti) and geometrical (E,Z) stereochemistry.

STEREOCONTROLLED (E, Z AND ERYTHRO, THREO) SYNTHESIS OF β-HYDROXYALLYLIC SULPHIDES

All four isomers of substituted 3-alkylthio-4-hydroxybutenes have been synthesised: both the geometry of the double bond and the relative stereochemistry of the two chiral centres are controlled.