1017246-22-8

Basic information

• Product Name: ((3R,4R,E)-6-cyclohexyl-2,4-dimethylhexa-1,5-dien-3-yloxy)triethylsilane
• Synonyms: ((3R,4R,E)-6-cyclohexyl-2,4-dimethylhexa-1,5-dien-3-yloxy)triethylsilane
• CAS NO: 1017246-22-8
• Molecular Weight: 322.607
• Mol File: 1017246-22-8.mol

Chemical Properties

• CAS DataBase Reference: ((3R,4R,E)-6-cyclohexyl-2,4-dimethylhexa-1,5-dien-3-yloxy)triethylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: ((3R,4R,E)-6-cyclohexyl-2,4-dimethylhexa-1,5-dien-3-yloxy)triethylsilane(1017246-22-8)
• EPA Substance Registry System: ((3R,4R,E)-6-cyclohexyl-2,4-dimethylhexa-1,5-dien-3-yloxy)triethylsilane(1017246-22-8)

Safety Data

• Hazardous Substances Data: 1017246-22-8(Hazardous Substances Data)

Upstream product

• 1017246-31-9 (3R,4R,E)-6-cyclohexyl-2,4-dimethylhexa-1,5-dien-3-ol 
• 79271-56-0 triethylsilyl trifluoromethyl sulfonate 

Downstream Products

• 1017246-23-9 (2S,3R,4R,E)-6-cyclohexyl-2,4-dimethyl-3-(triethylsilyloxy)hex-5-en-1-ol 

Relevant articles and documents

Asymmetric catalysis route to anti,anti stereotriads, illustrated by applications

(Chemical Equation Presented) A short sequence based on asymmetric catalysis, chirality transfer, and an optimized carbometallation protocol gave an anti,anti stereotriad building block in six steps. Both enantiomers of the chirality source, N-methyl ephedrine, are inexpensive, and the auxiliary is recoverable. In one chiral series, the building block was converted to the B-2 intermediate in Miyashita's synthesis of scytophycin C; in the enantiomeric series, it was converted to a key intermediate for aplyronine A and to the polyketide cap for the callipeltins.