1017584-78-9Relevant articles and documents
Highly enantioselective hetero-diels-alder reaction of frans-1-methoxy-2- methyl-3-trimethylsiloxybuta-1, 3-diene with aromatic and aliphatic aldehydes catalyzed by 3-substituted BINOL-titanium complex
Yang, Xin-Bin,Feng, Jie,Zhang, Ji,Wang, Na,Wang, Li,Liu, Jun-Liang,Yu, Xiao-Qi
, p. 1299 - 1302 (2008)
3-Diphenylhydroxymethyl-substituted BINOL-titanium complex prepared in situ was found to be a highly efficient catalyst for hetero-Diels-Alder reaction of diene 1 with both aromatic and aliphatic aldehydes to give 2,5-disubstituted dihydropyrone in up to 99% yield and 99% ee.