101772-33-2Relevant articles and documents
Superoxide Anion Efficiently Performs the Oxidative Cleavage of C=NOH Bonds of Amidoximes and N-hydroxyguanidines with Formation of Nitrogen Oxides
Sennequier, Nicolas,Boucher, Jean-Luc,Battioni, Pierrette,Mansuy, Daniel
, p. 6059 - 6062 (1995)
Potassium superoxide stoechiometrically reacts with arylamidoximes with the selective formation of the corresponding benzamide and nitrogen oxides (mainly NO2-) in high yield.A similar oxidative cleavage of the C=NOH bond of N-hydroxy-arylguanidines also occurs upon reaction with KO2; the yield of the corresponding urea is lower and large amounts of the corresponding cyanamide are also formed.The significance of this reaction of O2.- with compounds containing a C=NOH bond in the biological formation of nitrogen oxides including NO is discussed.
A series of 2, 4, 5-trisubstituted oxazole: Synthesis, characterization and DFT modelling
Kadam, Vinay S.,Shaikh, Saminaparwin G.,Patel, Arun L.
, p. 181 - 188 (2016/03/12)
A new series of 2,4,5-trisubstituted oxazole were synthesized with good yields using simple methodology. All the compounds were thoroughly characterized by IR, NMR (1H and 13C) and mass spectrometry and structures of 2-(4-butyloxyphenyl)-4,5-dimethyloxazole (5b) and 4,5-dimethyl-2-(4-(octyloxy)phenyl)oxazole(5e) were unambiguously determined by X-ray crystallography. Evidently, the crystal structures of these compounds showed C-HaN and C-HaO intermolecular interactions. The electronic structures of these compounds were also studied by DFT at B3LYP/6-311G ++ level of theory.
