101927-03-1Relevant articles and documents
Palladium(2+)-Catalyzed Intramolecular Aminocarbonylation of 3-Hydroxy-4-pentenylamines and 4-Hydroxy-5-hexenylamines
Tamaru, Yoshinao,Hojo, Makoto,Yoshida, Zen-ichi
, p. 5731 - 5741 (2007/10/02)
Palladium(2+) salt, in the presence of CuCl2 as an oxidant, catalyzes an intramolecular aminocarbonylation of N-protected 3-hydroxy-4-pentenylamines under 1 atm of carbon monoxide and selectively provides cis-3-hydroxypyrrolidine-2-acetic acid lactones.N-
Stereoselective Intramolecular Aminocarbonylation of 3-Hydroxypent-4-enylamides Catalyzed by Palladium
Tamaru, Yoshinao,Kobayashi, Takuji,Kawamura, Shin-ichi,Ochiai, Hirofumi,Yoshida, Zen-ichi
, p. 4479 - 4482 (2007/10/02)
The urethanes and tosamides of 3-Hydroxypent-4-enylamine and its C1-C4 substituted derivatives undergo the palladium catalyzed intramolecular aminocarbonylation (0.1 equiv of PdCl2, 3.0 equiv of CuCl2, 3.0 equiv of NaOAc i