101934-23-0

Basic information

• Product Name: 1-(p-methoxyphenyl)-t-2-methylcyclopentan-r-1-ol
• Synonyms: 1-(p-methoxyphenyl)-t-2-methylcyclopentan-r-1-ol
• CAS NO: 101934-23-0
• Molecular Weight: 206.285
• Mol File: 101934-23-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-(p-methoxyphenyl)-t-2-methylcyclopentan-r-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(p-methoxyphenyl)-t-2-methylcyclopentan-r-1-ol(101934-23-0)
• EPA Substance Registry System: 1-(p-methoxyphenyl)-t-2-methylcyclopentan-r-1-ol(101934-23-0)

Safety Data

• Hazardous Substances Data: 101934-23-0(Hazardous Substances Data)

Upstream product

• 1120-72-5 2-Methylcyclopentanone 
• 13139-86-1 4-methoxyphenyl magnesium bromide 
• 94-30-4 ethyl 4-methoxybenzoate 
• 63452-95-9 1,4-bis(bromomagnesio)pentane 

Downstream Products

• 6397-82-6 4'-methoxyhexanophenone 

Relevant articles and documents

Catalytic Ring-Opening of Cyclic Alcohols Enabled by PCET Activation of Strong O-H Bonds

We report a new photocatalytic protocol for the redox-neutral isomerization of cyclic alcohols to linear ketones via C-C bond scission. Mechanistic studies demonstrate that key alkoxy radical intermediates in this reaction are generated via the direct homolytic activation of alcohol O-H bonds in an unusual intramolecular PCET process, wherein the electron travels to a proximal radical cation in concert with proton transfer to a weak Br?nsted base. Effective bond strength considerations are shown to accurately forecast the feasibility of alkoxy radical generation with a given oxidant/base pair.

Reaction of 1,4-Bis(bromomagnesio)pentane and 1,5-Bis(bromomagnesio)hexane with Carboxylic acid Esters. A Useful, Highly Stereoselective Annelation

1,4-Bis(bromomagnesio)pentane and 1,5-bis(bromomagnesio)hexane have been prepared in THF solution, when treated with carboxylic acid esters, they afford trans diastereomeric bisubstituted cycloalkanols via a highly diastereoselective intramolecular Grignard reaction.