1019475-70-7Relevant academic research and scientific papers
CuI nanoparticles as recyclable heterogeneous catalysts for C-N bond formation reactions
Kumar, Manoranjan,Bhatt, Vinod,Nayal, Onkar S.,Sharma, Sushila,Kumar, Vishal,Thakur, Maheshwar S.,Kumar, Neeraj,Bal, Rajaram,Singh, Bikram,Sharma, Upendra
, p. 2857 - 2864 (2017)
Herein, copper iodide nanoparticles (NPs) are reported for the reductive amination of carbonyl compounds for the first time. The generated NPs were characterized by TEM, EDX, XRD and XPS analyses. The XRD patterns, XPS, and EDX analysis confirmed that the resulting NPs were CuI instead of Cu. The TEM images of CuI exhibited the size of monodispersed spherical NPs in the range of 4 ± 2 nm. These generated NPs can be used as versatile heterogeneous catalysts for important organic transformations. As a proof of concept, CuI NPs were successfully applied as heterogeneous catalysts for the synthesis of secondary amines, amides and triazoles. CuI NPs can be easily recovered and recycled up to six times.
Enantioselective organocatalytic reductive amination of aliphatic ketones by benzothiazoline as hydrogen donor
Saito, Kodai,Akiyama, Takahiko
, p. 4573 - 4575 (2012/06/15)
The chiral phosphoric acid-catalyzed enantioselective reductive amination of aliphatic ketones with aromatic amines was successfully achieved by the use of benzothiazoline as the hydrogen donor. Corresponding chiral aliphatic amines were obtained with exc
