10196-39-1

Basic information

• Product Name: 3,3-Diethyloxetane
• Synonyms: 3,3-Diethyloxetane
• CAS NO: 10196-39-1
• Molecular Formula: C₇H₁₄O
• Molecular Weight: 114.1855
• Mol File: 10196-39-1.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 128.4°Cat760mmHg
• Flash Point: 24°C
• Appearance: /
• Density: 0.842g/cm³
• Vapor Pressure: 13mmHg at 25°C
• Refractive Index: 1.415
• CAS DataBase Reference: 3,3-Diethyloxetane(CAS DataBase Reference)
• NIST Chemistry Reference: 3,3-Diethyloxetane(10196-39-1)
• EPA Substance Registry System: 3,3-Diethyloxetane(10196-39-1)

Safety Data

• Hazardous Substances Data: 10196-39-1(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Tetrahedron Letters, 8, p. 4973, 1967 DOI: 10.1016/S0040-4039(01)89948-2

InChI:InChI=1/C7H14O/c1-3-7(4-2)5-8-6-7/h3-6H2,1-2H3

Upstream product

• 40894-15-3 (CH₃CH₂CH₂CH₂)3SnOCH₂C(C₂H₅)2CH₂Br 
• 40894-02-8 2-bromomethyl-2-ethyl-butan-1-ol 
• 13423-63-7 5,5-diethyl-1,3-dioxan-2-one 

Downstream Products

• 18371-13-6 2-Methyl-2-ethyl-1-butanol 

Relevant articles and documents

DECOMPOSITION OF CARBONATE ESTERS OF 1,3-DIOLS. THE CHEMISTRY OF 1,3-BIFUNCTIONAL SYSTEMS, XXVI

The decomposition reactions of three cyclic carbonates and, in order to establish the reaction mechanisms, the corresponding diols were studied in presence of KOH, KCN and LiCl.Besides the previously known transformations (fragmentation yielding oxo compounds; CO2 elimination to give oxetanes; fragmentation to olefins), a new reaction of high selectivity has been found.On the action of a large excess of KOH, the carbonate esters of 1,3-diols are transformed into alcohols containing one carbon atom less than the correponding diols.