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1019600-58-8

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1019600-58-8 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1019600-58-8 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,0,1,9,6,0 and 0 respectively; the second part has 2 digits, 5 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 1019600-58:
(9*1)+(8*0)+(7*1)+(6*9)+(5*6)+(4*0)+(3*0)+(2*5)+(1*8)=118
118 % 10 = 8
So 1019600-58-8 is a valid CAS Registry Number.

1019600-58-8Downstream Products

1019600-58-8Relevant articles and documents

Catalyst-free photoinduced selective oxidative C(sp3)-C(sp3) bond cleavage in arylamines

Duan, Wentao,Lian, Qi,Wang, Songping,Wei, Wentao,Zhou, Jingwei

supporting information, p. 3261 - 3267 (2021/05/21)

Due to the directional nature of sp3-hybridized orbitals and the absence of π-orbitals, the oxidative cleavage of the kinetically and thermodynamically stable C(sp3)-C(sp3) bond is extremely difficult and remains scarcely explored. In this work, under the double argument of quantum mechanics (QM) computations and meticulous experiments on our well-designed C-C single bond cleavage mechanism, we discovered a means of photoinduced selective oxidative C(sp3)-C(sp3) bond cleavage in arylamines, easily achieved by simple visible light irradiation using O2as a benign oxidant under very mild conditions. The utility of our methodology was demonstrated by the C(sp3)-C(sp3) bond cleavage in morpholine/piperazine arylamines with excellent functional group tolerance. Importantly, our methodology is noteworthy, not only in that it does not require any catalysts, but also in that it provides valuable possibilities for the scalable functionalization of clinical drugs and natural products.

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