102-26-1

Basic information

• Product Name: 1,3,5-Triazine, 2,4,6-triethylhexahydro-
• Synonyms: 2,4,6-triethylhexahydro-1,3,5-triazine
• CAS NO: 102-26-1
• Molecular Formula: C₉H₂₁N₃
• Molecular Weight: 171.28314
• EINECS: 203-018-9
• Mol File: 102-26-1.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 190°Cat760mmHg
• Flash Point: 56.6°C
• Appearance: /
• Density: 0.826g/cm³
• Vapor Pressure: 0.553mmHg at 25°C
• Refractive Index: 1.414
• CAS DataBase Reference: 1,3,5-Triazine, 2,4,6-triethylhexahydro-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3,5-Triazine, 2,4,6-triethylhexahydro-(102-26-1)
• EPA Substance Registry System: 1,3,5-Triazine, 2,4,6-triethylhexahydro-(102-26-1)

Safety Data

• Hazardous Substances Data: 102-26-1(Hazardous Substances Data)

Usage

General Description

1,3,5-Triazine, 2,4,6-triethylhexahydro- is a chemical compound with a complex molecular structure. It belongs to the triazine class of organic compounds and is characterized by a six-membered ring containing three nitrogen atoms and three carbon atoms. Its precise properties and uses would depend on the specific context of its application within the field of chemistry.

Synthesis Reference(s)

The Journal of Organic Chemistry, 38, p. 3288, 1973 DOI: 10.1021/jo00959a010

InChI:InChI=1/C9H21N3/c1-4-7-10-8(5-2)12-9(6-3)11-7/h7-12H,4-6H2,1-3H3

Upstream product

• 4753-69-9 propan-1-imine 
• 765-30-0 Cyclopropylamine 
• 123-38-6 propionaldehyde 
• 104410-31-3 C₁₆H₁₅NO 

Downstream Products

• 123-38-6 propionaldehyde 

Relevant articles and documents

Synthesis of 5-methylidenehexahydropyrrolo[l,2-a]imidazoles and 6-methylideneoctahydropyrrolo[l,2-a]pyrimidines by the reaction of 1-alkynyl-1-chlorocyclopropanes with lithium derivatives of 1,2- and 1,3-diaminoalkanes

A reaction of 1-alkynyl-1-chlorocyclopropanes with excess of lithium derivative of 1,2-diaminoethane leads to 5-methylidenehexahydropyrrolo[l,2-a] imidazoles in 35-72% yields, whereas analogous reaction with lithium derivative of 1,3-diaminopropane gives 6-methyl-ideneoctahydropyrrolo[l,2-a]pyrimidine in up to 50% yield. A mechanism of these unusual multi-step processes includes dehydrochlorination of 1-alkynyl-1-chlorocyclopropanes to form conjugated alkynylcyclopropenes capable of addition of monoalkylamide ions at the double bond, leading to the corresponding secondary cyclopropylamines; the latter under the reaction conditions isomerize to the linear imines, which further undergo a cascade cyclization with sequential involvement of the C=N and C≡C bonds.

SYNTHESE D'IMINES LINEAIRES NON-STABILISEES PAR REACTIONS GAZ-SOLIDE SOUS VIDE(1).

Unstabilized imines are synthetized in gram-scale by vacuum dehydrochlorination of N-chloroalkylamines and by vacuum dehydrocyanation of α-aminonitriles on solid base.All the new compounds are characterized at low temperature by 1H, 13C NMR and IR spectroscopy.

Pyridines and dihydropyridines

A process of preparing alkyl (or aralkyl) pyridines and N-substituted alkyl (or aralkyl) dihydropyridines which comprises treating a2,5,6,8,9-pentaalkyl (or aralkyl) substituted 1,3,7-triazabicyclo (3,3,1) non-3-ene with a Lewis acid.