102000-72-6Relevant articles and documents
Synthesis of 2,1-Borazaroquinolines and 2,1-Borazaroisoquinolines from Vinylaminopyridines and Potassium Organotrifluoroborates by Microwave-Assisted Heating
Snchez Casado, M. Rosa,Ciordia Jimnez, Myriam,Ariza Bueno, Manuela,Barriol, Morgane,Leenaerts, Joseph E.,Pagliuca, Chiara,Martnez Lamenca, Carolina,De Lucas, Ana Isabel,Garca, Arnzazu,Trabanco, Andrs A.,Rombouts, Frederik J. R.
, p. 5221 - 5229 (2015)
Azaborines are an emerging class of compounds with applications in medicinal chemistry and materials science. The synthesis of a wide variety of borazaronaphthalenes has been reported in the last decade. However, access to other borazaro derivatives has been limited. A new approach to synthesize 2,1-borazaroquinolines and 2,1-borazaroisoquinolines from (vinylamino)pyridines and potassium organotrifluoroborates using microwave-assisted heating is reported. A substituted diverse set of new azaborines has been synthesized by this method, providing the first access to a family of 2,1-borazaroquinolines and 2,1-borazaroisoquinolines.
