102004-64-8

Basic information

• Product Name: benzyl 2-(azepan-1-yl)acetate
• Synonyms: benzyl 2-(azepan-1-yl)acetate
• CAS NO: 102004-64-8
• Molecular Weight: 247.337
• Mol File: 102004-64-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: benzyl 2-(azepan-1-yl)acetate(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl 2-(azepan-1-yl)acetate(102004-64-8)
• EPA Substance Registry System: benzyl 2-(azepan-1-yl)acetate(102004-64-8)

Safety Data

• Hazardous Substances Data: 102004-64-8(Hazardous Substances Data)

Upstream product

• 111-49-9 hexamethylene imine 
• 140-18-1 Benzyl chloroacetate 
• 52703-80-7 2-(azepan-1-yl)acetic acid 
• 100-51-6 benzyl alcohol 

Relevant articles and documents

Functional-Group-Tolerant, Silver-Catalyzed N-N Bond Formation by Nitrene Transfer to Amines

Silver(I) promotes the highly chemoselective N-amidation of tertiary amines under catalytic conditions to form aminimides by nitrene transfer from PhI NTs. Remarkably, this transformation proceeds in a selective manner in the presence of olefins and other functional groups without formation of the commonly observed aziridines or C-H insertion products. The methodology can be applied not only to rather simple tertiary amines but also to complex natural molecules such as brucine or quinine, where the products derived from N-N bond formation were exclusively formed. Theoretical mechanistic studies have shown that this selective N-amidation reaction proceeds through triplet silver nitrenes.