1020183-53-2Relevant academic research and scientific papers
An efficient methodology to substituted furans via oxidation of functionalized α-diazo-β-ketoacetates
Truong, Phong,Xu, Xinfang,Doyle, Michael P.
scheme or table, p. 2093 - 2096 (2011/05/09)
DMDO oxidation of functionalized α-diazo-β-ketoacetates, formed by zinc triflate catalyzed Mukaiyama-aldol condensation of methyl diazoacetoacetate with aldehydes, occurred in quantitative yield to form dihydrofuranols that undergo acid catalyzed dehydrat
Construction of higly functionalized diazoacetoacentates via catalytic Mukaiyama-Michael reactions
Liu, Yu,Zhang, Yu,Jee, Noel,Doyle, Michael P.
supporting information; experimental part, p. 1605 - 1608 (2009/04/10)
Functionalized diazo acetoacetates are prepared by an efficient Mukaiyama-Michael reaction between methyl 3-(trialkylsilanoxy)-2-diazo-3- butenoate and α,ss-unsaturated enones. Vinyl ether and ketone derivatives are both accessible in good to excellent yi
