1020396-85-3Relevant academic research and scientific papers
Catalyst self-adaptation in conjugate addition to nitroalkenes and nitroacrylates: Instant chirality control in diphenylmethane-based phosphoramidite ligands
Wakabayashi, Kazuki,Aikawa, Kohsuke,Kawauchi, Susumu,Mikami, Koichi
, p. 5012 - 5013 (2008)
The tropos diphenylmethane-based phosphoramidite ligand (A) provides high catalytic activity and enantioselectivity in the Cu catalysis of conjugate addition to nitroalkenes and nitroacrylate, by virtue of instant chirality control in A. Copyright
Chirality control of tropos diphenylmethane-derived phosphoramidites by chiral dienes: Its application to asymmetric Michael addition
Wakabayashi, Kazuki,Aikawa, Kohsuke,Mikami, Koichi
experimental part, p. 927 - 943 (2010/10/20)
The Rh complex of tropos diphenylmethane-derived phosphoramidite could be chirally controlled to adopt single chiral conformation upon addition of a chiral diene. In the asymmetric Michael addition of α-cyanocarboxylates catalyzed by the Rh complexes, the
