Cas 102045-27-2,(3aR,3bS,7aS,7bS)-7-Oxo-decahydro-cyclopenta[3,4]cyclobuta[1,2]benzene-3b-carboxylic acid (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenyl-ethyl)-cyclohexyl ester

102045-27-2

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Basic information

Product Name: (3aR,3bS,7aS,7bS)-7-Oxo-decahydro-cyclopenta[3,4]cyclobuta[1,2]benzene-3b-carboxylic acid (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenyl-ethyl)-cyclohexyl ester
Synonyms:
CAS NO:102045-27-2
Molecular Formula:
Molecular Weight: 422.608
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: (3aR,3bS,7aS,7bS)-7-Oxo-decahydro-cyclopenta[3,4]cyclobuta[1,2]benzene-3b-carboxylic acid (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenyl-ethyl)-cyclohexyl ester(CAS DataBase Reference)
NIST Chemistry Reference: (3aR,3bS,7aS,7bS)-7-Oxo-decahydro-cyclopenta[3,4]cyclobuta[1,2]benzene-3b-carboxylic acid (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenyl-ethyl)-cyclohexyl ester(102045-27-2)
EPA Substance Registry System: (3aR,3bS,7aS,7bS)-7-Oxo-decahydro-cyclopenta[3,4]cyclobuta[1,2]benzene-3b-carboxylic acid (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenyl-ethyl)-cyclohexyl ester(102045-27-2)

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Hazard Codes: N/A
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Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
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Hazardous Substances Data: 102045-27-2(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 102045-27-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,0,2,0,4 and 5 respectively; the second part has 2 digits, 2 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 102045-27:
(8*1)+(7*0)+(6*2)+(5*0)+(4*4)+(3*5)+(2*2)+(1*7)=62
62 % 10 = 2
So 102045-27-2 is a valid CAS Registry Number.

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102045-27-2Relevant academic research and scientific papers

ASYMMETRIC INDUCTION IN MIXED PHOTOADDITIONS. EFFECT OF SOLVENT, ALKENE CONCENTRATION AND TEMPERATURE.

Lange, Gordon L.,Decicco, Carl,Lee, Moses

, p. 2833 - 2836 (1987)

In mixed photoadditions with the chiral auxiliary in either the enone or the alkene component, it was found that changing the polarity of the solvent or the temperature of the irradiation had a marked effect on the extent of asymmetric induction.

ASYMMETRIC INDUCTION IN SIMPLE PHOTOADDITIONS

Lange, G. L.,Decicco, C.,Tan, S. L.,Chamberlain, G.

, p. 4707 - 4710 (2007/10/02)

Photochemical cycloaddition of cyclopentene with enone esters 1 containing different chiral auxiliaries yielded anti and syn adducts 2 and 3 in good yield and with moderate to high (79percent) enantiomeric excesses.

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