1020653-85-3Relevant academic research and scientific papers
On the synthesis of vinyl and phenyl C-furanosides by stereospecific debenzylative cycloetherification
Cribiù, Riccardo,Eszter Borbas,Cumpstey, Ian
experimental part, p. 2022 - 2031 (2009/07/18)
Open-chain benzyl-ether-protected polyols in which one of the alcohols is either allylic or benzylic are synthesised by addition of organometallic vinyl or phenyl reagents to benzyl-ether-protected carbohydrate hemiacetals. The diastereoselectivity of add
Stereospecific debenzylative cycloetherification of carbohydrate-derived allylic alcohols, ethers and esters to form vinyl C-furanosides
Cribiu, Riccardo,Cumpstey, Ian
, p. 1246 - 1248 (2008/12/21)
Benzyl ether protected polyhydroxylated alkene compounds containing allylic alcohol, ether or ester functionality undergo a stereospecific cyclisation reaction upon treatment with TFA-acetonitrile-toluene with inversion of configuration at the allylic position and loss of a benzyl ether to give tetrahydrofurans. The Royal Society of Chemistry.
