102093-93-6

Basic information

• Product Name: 2,5-anhydro-3,4-di-O-benzyl-1-bromo-1-deoxy-D-glucitol
• Synonyms: 2,5-anhydro-3,4-di-O-benzyl-1-bromo-1-deoxy-D-glucitol
• CAS NO: 102093-93-6
• Molecular Weight: 407.304
• Mol File: 102093-93-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2,5-anhydro-3,4-di-O-benzyl-1-bromo-1-deoxy-D-glucitol(CAS DataBase Reference)
• NIST Chemistry Reference: 2,5-anhydro-3,4-di-O-benzyl-1-bromo-1-deoxy-D-glucitol(102093-93-6)
• EPA Substance Registry System: 2,5-anhydro-3,4-di-O-benzyl-1-bromo-1-deoxy-D-glucitol(102093-93-6)

Safety Data

• Hazardous Substances Data: 102093-93-6(Hazardous Substances Data)

Upstream product

• 102093-92-5 Acetic acid (2R,3R,4S)-3,4-bis-benzyloxy-5-bromomethyl-tetrahydro-furan-2-ylmethyl ester 
• 160549-10-0 2,3,5-tri-O-benzyl-D-arabinofuranose 
• 93125-78-1 (R)-1,3,4-Tris-benzyloxy-hex-5-en-2-ol 
• 102093-89-0 C₃₄H₃₆O₄ 
• 102208-54-8 2,5-anhydro-3,4,6-tri-O-benzyl-D-glucitol 
• 102093-88-9 2,5-anhydro-3,4,6-tri-O-benzyl-1-bromo-1-deoxy-D-glucitol 
• 109065-81-8 C₂₇H₂₉BrHgO₄ 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 157363-84-3 1,2:5,6-dianhydro-3,4-di-O-benzyl-L-iditol 
• 36199-02-7 3,4-di-O-benzyl-D-mannitol 
• 172147-87-4 (2R,3R,4R,5R)-3,4-Bis-benzyloxy-1,6-bis-(tert-butyl-dimethyl-silanyloxy)-hexane-2,5-diol 
• 172147-86-3 Methanesulfonic acid (1R,2S,3S,4R)-2,3-bis-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-1-(tert-butyl-dimethyl-silanyloxymethyl)-4-methanesulfonyloxy-pentyl ester 

Downstream Products

• 102093-94-7 Phosphoric acid (2R,3R,4S)-3,4-bis-benzyloxy-5-bromomethyl-tetrahydro-furan-2-ylmethyl ester diphenyl ester 
• 115224-25-4 ((2R,3S,4S,5R)-3,4-Dihydroxy-5-phosphonooxymethyl-tetrahydro-furan-2-ylmethyl)-phosphonic acid 
• 1309855-93-3 1-(3,4,6-tri-O-acetyl-2,5-anhydro-1-deoxy-D-glucitolyl)-4-(4-N,N-dimethylaminophenyl)-[1,2,3]-triazole 
• 1309855-95-5 1-(3,4,6-tri-O-acetyl-2,5-anhydro-1-deoxy-D-glucitolyl)-4-(4-methoxyphenyl)-[1,2,3]-triazole 
• 1309855-98-8 1-(3,4,6-tri-O-acetyl-2,5-anhydro-1-deoxy-D-glucitolyl)-4-(1-hydroxy-1-phenylmethyl)-[1,2,3]-triazole 
• 1309855-99-9 1-(3,4,6-tri-O-acetyl-2,5-anhydro-1-deoxy-D-glucitolyl)-4-(1-hydroxycyclohexyl)-[1,2,3]-triazole 
• 1309856-04-9 1-(3,4,6-tri-O-acetyl-2,5-anhydro-1-deoxy-D-glucitolyl)-4-(4-aminophenyl)-[1,2,3]-triazole 
• 1309856-08-3 1-(3,4,6-tri-O-acetyl-2,5-anhydro-1-deoxy-D-glucitolyl)-4-(4-hydroxymethylphenyl)-[1,2,3]-triazole 
• 1309856-11-8 1-(2,5-anhydro-1-deoxy-D-glucitolyl)-4-(4-N,N-dimethylaminophenyl)-[1,2,3]-triazole 
• 1309856-13-0 1-(2,5-anhydro-1-deoxy-D-glucitolyl)-4-(4-methoxyphenyl)-[1,2,3]-triazole 
• 1309856-17-4 1-(2,5-anhydro-1-deoxy-D-glucitolyl)-4-(1-hydroxy-1-phenylmethyl)-[1,2,3]-triazole 
• 1309856-18-5 1-(2,5-anhydro-1-deoxy-D-glucitolyl)-4-(1-hydroxycyclohexyl)-[1,2,3]-triazole 
• 1309856-23-2 1-(2,5-anhydro-1-deoxy-D-glucitolyl)-4-(4-aminophenyl)-[1,2,3]-triazole 
• 1309856-24-3 1-(2,5-anhydro-1-deoxy-6-sulfo-D-glucitolyl)-4-(4-N,N-dimethylaminophenyl)-[1,2,3]-triazole 

Relevant articles and documents

An efficient approach to 2,5-anhydro-glucitol-based 1′-homo-N- nucleoside mimetics

This Letter describes an efficient synthesis of a range of 1′-homo-N-nucleoside mimetics with a series of 4-substituted 1,2,3-triazoles replacing the natural nucleobase. The synthesis of 6-O-monosulfated 1′-homo-N-nucleoside mimetic derivatives is also discussed.

SYNTHESIS OF C-ARABINOFURANOSYL COMPOUNDS. PHOSPHONATE AND CARBOXYLATE ISOESTERS OF D-ARABINOSE 1,5-BISPHOSPHATE

Electrophile-mediated cyclization of 3,4,6-tri-O-benzyl-1,2-dideoxy-D-arabino-hex-1-enitol with N-bromosuccinimide yielded primarily 2,5-anhydro-3,4,6-tri-O-benzyl-1-bromo-1-deoxy-D-glucitol (10).This apparently kinetically controlled reaction was of key