102108-90-7Relevant academic research and scientific papers
Halides-based electrophiles mediated epoxide ring-opening reactions of α,β-epoxysulfoxides in C6-series : Deoxygenation versus dehydration and an overall 1,2-keto transposition
Barillier, Daniel,Levillain, Jocelyne,Vazeux, Michel
, p. 5413 - 5424 (2007/10/02)
New syntheses of α-thiosubstituted carbonyl compounds with the carbonyl carbon being the one that originally does not carry the sulfoxide group from six-membered ring α,β-epoxysulfoxides and several halides-based electrophiles are described. Mechanistic considerations for deoxygenation as well as dehydration reactions are also discussed. In addition, methodology for achieving 1,2-carbonyl transposition starting with isomerically pure cyclohexenyl sulfides derived from isophorone and cholestan-3-one is briefly reported.
On the Stereochemistry and Mechanism of the Ozonation of Some Six-Membered Ring Vinyl Sulfides
Barillier, Daniel,Vazeux, Michel
, p. 2276 - 2285 (2007/10/02)
Allylic alcohols 3 and α,β-epoxy sulfoxides 6/7 were the partial cleavage products isolated from the ozonation of six-membered-ring vinyl sulfides 1 with respectively stoichiometric and double amounts of ozone.They were characterized by spectroscopic meth
