102117-79-3Relevant academic research and scientific papers
CATALYTIC REARRANGEMENT OF THE γ-CHLOROALLYL ETHERS OF PHENOLS
Andreev, N. A.,Bunina-Krivorukova, L. I.,Levashova, V. I.,Aleksandrova, E. K.
, p. 1398 - 1402 (2007/10/02)
The catalytic rearrangement of the γ-chloroallyl ethers of phenol, p- and o-cresol, p- and o-chlorophenol, and 2,4-dichlorophenol takes place by an intermolecular mechanism with the formation of alkenylphenols without inversion of the allylic unit.The transformation of the ethers with a CH3 group (ortho or para) in the benzene ring takes place under milder conditions than that of ethers with a chlorine atom at the same positions.
