102130-91-6

Basic information

• Product Name: (1S)-7-Isopropylidene-1,2,3,5,6,7,8,8aβ-octahydro-1β-hydroxy-1,4-dimethylazulen-6-one
• Synonyms: (1S)-7-Isopropylidene-1,2,3,5,6,7,8,8aβ-octahydro-1β-hydroxy-1,4-dimethylazulen-6-one;Neoprocurcumenol;(1S-cis)-2,3,5,7,8,8a-Hexahydro-1-hydroxy-1,4-dimethyl-7-(1-methylethylidene)-6(1H)-azulenone
• CAS NO: 102130-91-6
• Molecular Formula: C15H22O2
• Molecular Weight: 234.33398
• Mol File: 102130-91-6.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: (1S)-7-Isopropylidene-1,2,3,5,6,7,8,8aβ-octahydro-1β-hydroxy-1,4-dimethylazulen-6-one(CAS DataBase Reference)
• NIST Chemistry Reference: (1S)-7-Isopropylidene-1,2,3,5,6,7,8,8aβ-octahydro-1β-hydroxy-1,4-dimethylazulen-6-one(102130-91-6)
• EPA Substance Registry System: (1S)-7-Isopropylidene-1,2,3,5,6,7,8,8aβ-octahydro-1β-hydroxy-1,4-dimethylazulen-6-one(102130-91-6)

Safety Data

• Hazardous Substances Data: 102130-91-6(Hazardous Substances Data)

Usage

General Description

The chemical "(1S)-7-Isopropylidene-1,2,3,5,6,7,8,8aβ-octahydro-1β-hydroxy-1,4-dimethylazulen-6-one" is a complex organic compound with a bicyclic structure. It is a derivative of azulene, a natural compound found in certain essential oils. The chemical is characterized by an isopropylidene group and a hydroxy group attached to the azulene ring, along with methyl substituents at positions 1 and 4. It has the potential for various biological activities and is of interest for medicinal and synthetic purposes due to its unique structure. Its specific properties and potential applications may vary depending on the intended use and the context in which it is being studied.

Upstream product

• 32179-17-2 (4S,5S)-epoxy-(+)-4,5-dihydrogermacrone 
• 32179-17-2 (4S,5S)-(+)-germacrone 4,5-epoxide 

Relevant articles and documents

Structural diversity from the transannular cyclizations of natural germacrone and epoxy derivatives: A theoretical-experimental study

Treatment of germacrone (1) with different electrophiles, and of its epoxy derivatives germacrone-4,5-epoxide (2), germacrone-1,10-epoxide (3) and isogermacrone-4,5-epoxide (4) with Br?nsted/Lewis acids and Ti III, gives rise to a great structural diversity. Thus, by using a maximum of two steps, the production of more than 40 compounds corresponding to 14 skeletons is described. Computational calculations rationalizing the structural divergence produced are also described. Finally, since some of the compounds generated are bioactive natural sesquiterpenes, the mechanisms of formation of these substances will provide new insights in their biosynthesis. Copyright