102145-97-1Relevant academic research and scientific papers
Pinacol-Pinacolone Rearrangement on FeCl3 Modified Montmorillonite K10
Shinde, Ajit B.,Shrigadi, Nilesh B.,Bhat, Ramakrishna P.,Samant, Shriniwas D.
, p. 309 - 314 (2007/10/03)
Pinacol-pinacolone rearrangement was investigated over Fe-modified montmorillonite K10 catalysts in liquid phase. Exceptional activity was found to be associated with FeCl3 impregnated on K10 through its acetonitrile solution. 100% conversion of benzopinacol was observed in 10 minutes. The catalysts are recyclable.
Novel reductive couplinog-rearrangement of carbonyl compounds with metal/Lewis acid under irradiation of ultrasonic wave
Sato, Ryu,Nagaoka, Takeshi,Saito, Minoru
, p. 4165 - 4168 (2007/10/02)
Novel reductive coupling-rearrangement of carbonyl compounds such as benzophenones with Al or Zn/ AlCl3 in CH3CN under irradiation of ultrasonic wave gave benzopinacolones via epoxides in good yields.
