102146-12-3Relevant academic research and scientific papers
LEWIS ACID MEDIATED ALDOL CONDENSATIONS USING THIOESTER SILYL KETENE ACETALS
Gennari, Cesare,Beretta, M. Grazia,Bernardi, Anna,Moro, Giorgio,Scolastico, Carlo,Todeschini, Roberto
, p. 893 - 910 (2007/10/02)
BF3-OEt2 mediated thioester silylketene acetal additions to aldehydes are stereoconvergent and give high anti-syn ratios and good chemical yields.An acyclic transition state model was hypothesized in order to account for the observed selectivity.Theoretic
STEREOSELECTIVE ALDOL REACTIONS USING TiCl4 AS STEREOCHEMICAL TEMPLATE
Gennari, Cesare,Bernardi, Anna,Scolastico,Carlo,Potenza, Donatella
, p. 4129 - 4132 (2007/10/02)
TiCl4 mediated aldol condensations establish multiple contiguous chiral centers in an almost complete enantio- and diastereoselective way.
