1021493-41-3Relevant academic research and scientific papers
Synthesis of tetrasubstituted 2-aryl-3-arylsulfonyl pyrroles: Unexpected regioselectivity in directed ortho-metallation reactions
Bailey, Nick,Demont, Emmanuel,Garton, Neil,Seow, Hui-Xian
, p. 185 - 188 (2008/09/21)
3-Arylsulfonyl pyrroles can be readily obtained from 3-Br-TIPS pyrrole via halogen-metal exchange and subsequent sulfonylation. The regioselectivity of the subsequent directed ortho-metallation (DOM) reaction in order to functionalise the C-2 position dep
