1021497-64-2Relevant academic research and scientific papers
Synthesis, structure, and quaternization and complexation reactions of κ3SCS pincer palladium complexes having 3,5-pyridinediyl unit
Meguro, Hikaru,Koizumi, Take-aki,Yamamoto, Takakazu,Kanbara, Takaki
, p. 1109 - 1116 (2008/04/13)
The cyclopalladation of 3,5-bis(diphenylphosphinothioyl)pyridine afforded new κ3S,C,S-pincer palladium complexes with a σ-bond between Pd and 4C of the centered 3,5-pyridinediyl unit. By utilizing the quaternization and complexation ability of the pyridine imine nitrogen (Npy) atom, various new pincer-type complexes, including hetero-binuclear complexes, have been synthesized.
