102150-13-0Relevant articles and documents
Low Coordinated Phosphorus Compounds, 48. Synthesis of 1-Phosphaallenes
Appel, Rolf,Winkhaus, Volker,Knoch, Falk
, p. 2466 - 2472 (2007/10/02)
The new 1-phosphaallenes 3b, c were obtained by Wittig reaction of the phosphaketene 1 with the ylides 2b, c.Attempts to synthesize 1-phosphaallenes via an elimination of disiloxane from the addition product of ketene 5 and disilylphosphane 4b resulted in the formation of the dimeric 1-phosphaallene 9.Its structure was proved by X-ray analysis.