1021906-18-2Relevant academic research and scientific papers
Migration and insertion processes in the reactions of the hydrocarbyl-bridged unsaturated complexes [Mo2(μ5- C5H5)2(μ-R)(μ-PCy2)(CO) 2] (R = Me, CH2Ph, Ph) with CO and
Angeles Alvarez,Esther Garcia,Eugenia Martinez,Ramos, Alberto,Ruiz, Miguel A.
, p. 6293 - 6307 (2010/01/29)
The alkyl-bridged unsaturated complexes [Mo2Cp 2(μ-R)(μ-PCy2)(CO)2] (R = Me, CH 2Ph) react readily with CO (1 atm) at room temperature or below, but the products are strongly dependent on the alkyl br
Reactivity of the α-agostic methyl bridge in the unsaturated complex [Mo2(η5-C5H5) 2(μ-η1:η2-CH3)(μ- PCy2)(CO)2]: Migratory behavior and methylid
Alvarez, M. Angeles,Garcia-Vivo, Daniel,Garcia, M. Esther,Martinez, M. Eugenia,Ramos, Alberto,Ruiz, Miguel A.
, p. 1973 - 1975 (2009/02/01)
The bridging methyl ligand present in the title compound can migrate up to the cyclopentadienyl (Cp) site upon reaction with CO to achieve an overall exchange between the methyl and hydrogen (Cp) positions. In the presence of different metal-carbonyl comp
