Cas 102258-21-9,1-chloro-1-hydrido-1,3,5-tris(triphenylphosphine)-isocloso-1-ruthenadecaborane

102258-21-9

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Basic information

Product Name: 1-chloro-1-hydrido-1,3,5-tris(triphenylphosphine)-isocloso-1-ruthenadecaborane
Synonyms:
CAS NO:102258-21-9
Molecular Formula:
Molecular Weight: 1028.76
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: 1-chloro-1-hydrido-1,3,5-tris(triphenylphosphine)-isocloso-1-ruthenadecaborane(CAS DataBase Reference)
NIST Chemistry Reference: 1-chloro-1-hydrido-1,3,5-tris(triphenylphosphine)-isocloso-1-ruthenadecaborane(102258-21-9)
EPA Substance Registry System: 1-chloro-1-hydrido-1,3,5-tris(triphenylphosphine)-isocloso-1-ruthenadecaborane(102258-21-9)

Safety Data

Hazard Codes: N/A
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Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 102258-21-9(Hazardous Substances Data)

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102258-21-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 102258-21-9 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,0,2,2,5 and 8 respectively; the second part has 2 digits, 2 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 102258-21:
(8*1)+(7*0)+(6*2)+(5*2)+(4*5)+(3*8)+(2*2)+(1*1)=79
79 % 10 = 9
So 102258-21-9 is a valid CAS Registry Number.

102258-21-9Relevant academic research and scientific papers

Polyhedral ruthenaborane chemistry. Approaches to encapsulated boron cores. The isolation and characterisation of the partially encapsulated isocloso 10-vertex {RuB9} cluster compound [(PPh3)RuB 9H9{RuCl2

Kim, Young-Hee,Barton, Lawrence,Rath, Nigam P.,Kennedy, John D.

, p. 147 - 150 (2005)

[RuCl2(Ph3)2] with [arachno-B 9H14]- gives [(PPh3)RuB 9H9{RuCl2(PPh3)2} 2], which has an isocloso 10-vertex {RuB

Two Unusual closo-type Ruthenaboranes: Preparation, Molecular Structure, and Nuclear Magnetic Resonance Properties of and

Crook, Janet E.,Elrington, Margaret,Greenwood, Norman N.,Kennedy, John D.,Thornton-Pett, Mark,Woollins, J. Derek

, p. 2407 - 2416 (2007/10/02)

Reaction of arachno-- with under mild conditions gives the orange 10-vertex ruthenadecaborane in ca. 40percent yield.The molecular structure is based on an 'isocloso' C3v 1:3:3:3 RuB9 stack with the nine-co-ordinate metal occupying the unique six-connected apical position.The electronic structure may be interpreted either on the basis of a 'PSEPT-deficient' 2n-electron cluster with the metal having a straightforward 'conical' three-orbital contribution, or as a 'PSEPT-precise' (2n+2)-electron cluster with the metal having a four-orbital involvement, also conical, with the cluster.Similar bonding considerations apply to the red 11-vertex ruthenaundecaborane which is obtained in a yield of 80percent from the reaction of with closo-2- in refluxing ethanolic chloroform.The molecular structure is based on that of a closo-type C2v 1:2:4:2:2 RuB10 stack again with the metal occupying the unique six-connected apical position.Both compounds can be considered as having 'isocloso' structures derived from the complete capping of the open face of an arachno geometry to give a completely closed deltahedral cluster.