10228-83-8Relevant academic research and scientific papers
A method for the asymmetric hydrosilylation of N-aryl imines
Hansen, Marcus C.,Buchwald, Stephen L.
, p. 713 - 715 (2000)
graph presented The asymmetric reduction of N-aryl imines to yield chiral amines with enantiomeric excesses above 90% was achieved. Ethylenebis(η5-tetrahydroindenyl)titanium difluoride ((EBTHI)TiF2,1) was employed as the precatalyst
Commercial Supported Gold Nanoparticles Catalyzed Alkyne Hydroamination and Indole Synthesis
Liang, Shengzong,Hammond, Luisa,Xu, Bo,Hammond, Gerald B.
supporting information, p. 3313 - 3318 (2016/10/21)
Commercial gold nanoparticles supported on titanium dioxide (TiO2) were found to be a highly efficient catalyst for alkyne hydroamination. Terminal alkynes could easily undergo intermolecular hydroamination with low catalyst loadings (0.2 mol% Au) under solvent-free conditions. Indoles were efficiently synthesized using microwave heating through intramolecular hydroamination. (Figure presented.).
A Frustrated Lewis Pair Catalyzed Asymmetric Transfer Hydrogenation of Imines Using Ammonia Borane
Li, Songlei,Li, Gen,Meng, Wei,Du, Haifeng
supporting information, p. 12956 - 12962 (2016/10/13)
Inspired by the zwitterion species generated from the splitting of H2 by frustrated Lewis pairs, we put forward a novel frustrated Lewis pair by the combination of Hδ and Hδ incorporated Lewis acid and base together. Piers
Rhodium(III)-catalyzed hydroamination of aromatic terminal alkynes with anilines
Kumaran, Elumalai,Leong, Weng Kee
experimental part, p. 1068 - 1072 (2012/04/04)
The dinuclear Rh(III) species [Cp*RhCl2]2 catalyzes the hydroamination reaction between an aromatic terminal alkyne (ArCCH) and an aniline (Ar′NH2), in the presence of a salt additive, to afford the ketimine Ar′N=C(Me)(Ar). A reaction pathway has been proposed on the basis of experimental and computational studies.
Rhenium-catalyzed diastereoselective synthesis of aminoindanes via the insertion of allenes into a C-H bond
Kuninobu, Yoichiro,Yu, Peng,Takai, Kazuhiko
supporting information; experimental part, p. 4274 - 4276 (2010/11/24)
Figure Presented. Aminoindane derivatives were synthesized diastereoselectively by the treatment of aromatic imines with allenes in the presence of a catalytic amount of a rhenium complex, [HRe(CO)4] n. The allenes inserted into the
Role of noncovalent interactions in the enantioselective reduction of aromatic ketimines with trichlorosilane
Malkov, Andrei V.,Mariani, Andrea,MacDougall, Kenneth N.,Kocovsky, Pavel
, p. 2253 - 2256 (2007/10/03)
Asymmetric reduction of ketimines 1 with trichlorosilane can be catalyzed by a new N-methyl L-valine derived Lewis basic organocatalyst, such as 4d, with high enantioselectivity. The structure-reactivity investigation suggests hydrogen bonding and arene-arene interactions between the catalyst and the incoming imine as the main factor determining the enantiofacial selectivity.
