102301-89-3

Upstream product

• 14204-24-1 N-(phenylthio)succinimide 
• 102301-88-2 6-((E)-3-Hydroxy-2-methyl-propenyl)-1,3,5,6-tetrahydro-azepino[5,4,3-cd]indole-4,4-dicarboxylic acid dimethyl ester 
• 53704-09-9 dimethyl 2-aminomalonate 
• 112152-21-3 3-<(dimethylamino)methyl>-4-<(E)-4-<(tert-butyldimethylsilyl)oxy>-3-hydroxy-3-methyl-1-butenyl>indole 
• 102301-86-0 2-Amino-2-[4-((E)-3,4-dihydroxy-3-methyl-but-1-enyl)-1H-indol-3-ylmethyl]-malonic acid dimethyl ester 
• 102301-85-9 2-Amino-2-{4-[(E)-4-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-3-methyl-but-1-enyl]-1H-indol-3-ylmethyl}-malonic acid dimethyl ester 

Relevant academic research and scientific papers

A BIOMIMETIC ROUTE TO THE ERGOT DERAILMENT PRODUCTS, THE CLAVICIPITIC ACIDS - DETECTION OF A REACTIVE INTERMEDIATE BY (31)P NMR - SOME CHEMICAL UNDERPINNINGS FOR A PROPOSED INTERMEDIATE IN ERGOT ALKALOID BIOSYNTHESIS

A biomimetic route to the clavicipitic acids has been developed which is based on the Mitsunobu reaction of the diol 4a.