102333-76-6Relevant academic research and scientific papers
Vicarious Nucleophilic Substitution of Hydrogen in Nitroarenes by Carbanions of Alkyl Dichloroacetates. Some New Transformations of Chloro(nitroaryl)acetates
Makosza, Mieczyslaw,Sienkiewicz, Krzysztof,Wojciechowski, Krzysztof
, p. 850 - 852 (2007/10/02)
Vicarious Nucleophilic Substitution of Hydrogen in nitroarenes by ethyl dichloroacetate anion provides ethyl chloro(nitroaryl)acetates, which can be transformed into ethyl imino(nitroaryl)acetates and ethyl oxo(nitroaryl)acetates by treatment with sodium azide.
SYNTHESES D'ESTERS OU D'ACIDES α-HALOGENES A PARTIR DES GEM DICYANO EPOXIDES.
Robert, A.,Jaguelin, S.,Guinamant, J. L.
, p. 2275 - 2282 (2007/10/02)
α-halogeno esters or α-halogenoacids were easily prepared by selective one pot reaction of gem-dicyano epoxides with halohydric acids in an alcoholic or aqueous media.
ETUDE DE LA RECTIVITE D'YLURES DE SULFONIUM ET DE PYRIDINIUM STABILISES PAR UN GROUPEMENT CYANOFORMYLE.
Baudy-Floc'h, M.,Robert, A.
, p. 3297 - 3302 (2007/10/02)
The sulfonium and pyridinium ylides stabilized by a cyanoformyl group, in acidic medium, lead to sulfonium and pyridinium ketene salts.This originality has been used to prepare new stabilized ylides, or derivatives of substituted arylacetic acids or 4-hydroxy thiazoles.
