102334-11-2Relevant articles and documents
Ortho-Formylation of Anilines by Rearrangement of Bis(methylthio)methane-S-(N-aryl)imides
Claus, Peter K.,Jaeger, Emmerich,Setzer, Alexis
, p. 1017 - 1026 (2007/10/02)
By reaction of anilines with dithioacetals of formaldehyde and tert.butylhypochlorite the corresponding intermediate mono-sulfimides are formed which rearrange easily - after addition of triethylamine - to yield dithioacetals 5 of o-amino benzaldehydes. - Keywords: Sulfimides; Dithioacetals; Sigmatropic rearrangement