1023646-81-2Relevant articles and documents
Facile synthetic procedure for and electrochemical properties of hexa(2-thienyl)benzenes directed toward electroactive materials
Yoshida, Kenta,Morimoto, Ichiro,Mitsudo, Koichi,Tanaka, Hideo
, p. 2363 - 2365 (2008)
In the presence of RhCl3·3H2O and i-Pr2NEt, the cyclotrimerization of di(2-thienyl)acetylenes proceeded smoothly to afford hexa(2-thienyl)benzenes. CV analysis of the hexa(2-thienyl)benzenes showed that they may be useful
RhCl3/amine-catalyzed [2+2+2] cyclization of alkynes
Yoshida, Kenta,Morimoto, Ichiro,Mitsudo, Koichi,Tanaka, Hideo
, p. 5800 - 5807 (2008/09/21)
The RhCl3·3H2O/i-Pr2NEt-catalyzed [2+2+2] cyclotrimerization of alkynes has been achieved. The reaction can be widely used for various alkynes and provides tri- or hexa-substituted benzenes regioselectively in high yields. The [2+2+2] cycloaddition of diynes and alkynes is also developed, and it affords benzene derivatives in moderate to high yields.