102367-91-9Relevant academic research and scientific papers
Synthesis of Tetranitrotoluenes
Nielsen, Arnold T.,Christian, Stephen L.,Chafin, Andrew P.,Wilson, William S.
, p. 1714 - 1718 (2007/10/02)
New synthetic routes to the three isomeric tetranitrotoluenes 1-3 are described, including the previously unreported 2,3,4,5-tetranitrotoluene (1).Methods include peroxydisulfuric acid oxidation of trinitrotoluidines and hypophosphorous acid reduction of
Synthesis of Polynitrodiazophenols
Atkins, Ronald L.,Wilson, William S.
, p. 2572 - 2578 (2007/10/02)
The formation of diazophenols by nitration of suitably substituted anilines and rearrangement of the nitroaromatic nitramines so formed is presented.The scope of the reaction is discussed, and a mechanism for the nitramine/diazophenol rearrangement is proposed which is consistent with 15N-labeling experiments.
