102373-65-9Relevant academic research and scientific papers
Synthesis and alkali metal picrate extraction capabilities of novel, cage-functionalized, pyridine containing crown ethers and cryptands
Marchand, Alan P.,Chong, Hyun-Soon,Alihodzic, Sulejman,Watson, William H.,Bodige, Satish G.
, p. 9687 - 9696 (1999)
The syntheses of novel cage-functionalized crown ethers, 11-13, that contain one or more pyridyl units are reported. The results of alkali metal picrate extraction experiments performed by using 11 and 12 are compared with those obtained by using the corr
Large pKa shifts of α-carbon acids induced by copper(II) complexes
Zhong, Zhenjin,Postnikova, Brenda J.,Hanes, Robert E.,Lynch, Vincent M.,Anslyn, Eric V.
, p. 2385 - 2394 (2007/10/03)
A series of synthetic receptors (4-6) incorporating metal ions, specifically copper(II), were examined for their ability to enhance the acidity of active methylene compounds. The copper(II) complexes were observed to reduce the pKa of 1,3-diket
Metal ions co-operativity in the catalysis of the hydrolysis of a β-amino ester by a macrocyclic dinuclear Cu(II) complex
Scrimin, Paolo,Tecilla, Paolo,Tonellato, Umberto,Valle, Giovanni,Veronese, Andrea
, p. 527 - 538 (2007/10/02)
The macrocyclic receptor 3, featuring two diaminomethylpyridine moieties as ligand subunits and two diphenylmethane lipophilic spacers was synthesized and the crystal structure of its dinuclear Cu(II) complex, 3·2Cu, defined by X-ray analysis. From a kine
