102393-60-2Relevant academic research and scientific papers
THERMAL REARRANGEMENT OF FUNCTIONALIZED 1,2-DIVINYLCYCLOPROPANE SYSTEMS. A CONVENIENT SYNTHESIS OF SUBSTITUTED 4-CYCLOHEPTEN-1-ONES
Piers, Edward,Burmeister, Max S.,Reissig, Hans-Ulrich
, p. 180 - 187 (2007/10/02)
Reaction of the acyl chlorides 14-21 with lithium (phenylthio)(cis-2-vinylcyclopropyl)cuprate (2) provided the ketones 22-29.Compounds 22-25, upon treatment with i-Pr2NLi-Me3SiCl, were converted cleanly into the enol silyl ethers 30-33, which gave the 1,4
