1023973-09-2Relevant articles and documents
The Regiospecific Preparation of 2-Substituted Tribenzotriquinacenes
Saravanakumar, Rajendran,Markopoulos, Georgios,Bahrin, LucianGabriel,Jones, PeterG.,Hopf, Henning
, p. 453 - 456 (2013)
Several substituted tribenzotriquinacene derivatives (TBTQ) carrying functional groups exclusively in the 2-position (OMe, OH, Br, CHO, CN, styryl, etc.) have been prepared by our new synthesis of the tribenzotriquinacene framework. The route has been ext
Synthesis of chiral tetrahydrofurans via catalytic asymmetric [3 + 2] cycloaddition of heterosubstituted alkenes with oxiranes
Yuan, Xiao,Lin, Lili,Chen, Weiliang,Wu, Wangbin,Liu, Xiaohua,Feng, Xiaoming
, p. 1237 - 1243 (2016/02/19)
An efficient diastereo- and enantioselective [3 + 2] cycloaddition of heterosubstituted alkenes with oxiranes via selective C-C bond cleavage of epoxides has been developed. The reaction was catalyzed by a chiral N,N′-dioxide/Ni(II) catalyst, and a variety of chiral highly substituted tetrahydrofurans were obtained in up to 99% yield, 92/8 dr, and 99% ee.