102402-73-3Relevant academic research and scientific papers
Decarbopalladation of π-allylpalladium intermediates formed from palladium-catalyzed arylations of 3-allen-1-ols
Oh, Chang Ho,Jung, Seung Hyun,Bang, Su Youn,Park, Dai In
, p. 3325 - 3327 (2007/10/03)
eqution presented Unusual palladium-catalyzed arylative fragmentations of acyclic 3-allen-1-ols were observed. Oxidative addition of Pd(0) to aryl halides would form the arylpalladium halides, which added to the central carbon of allenes via carbopalladation to form the π-allylpalladium intermediates. The π-allylpalladium intermediates would be reductively eliminated via carbon-carbon cleavage to give the arylated dienes and the α-hydroxyalkylpalladium intermediates, which were further reductively eliminated to the corresponding aldehydes.
EFFICIENT PREPARATION OF POLYSUBSTITUTED 1,3-DIENES FROM α,α'-DIKETO SULFIDES
Nakayama, Juzo,Machida, Haruki,Saito, Ryuji,Akimoto, Keiichi,Hoshino, Masamatsu
, p. 1173 - 1176 (2007/10/02)
A series of polysubstituted 1,3-dienes were prepared in good overall yields in three steps starting from readily accessible α,α'-diketo sulfides.
