102402-86-8Relevant academic research and scientific papers
Catalytic B(C6F5)3[rad]H2O-promoted defluorinative functionalization of tertiary aliphatic fluorides
Dryzhakov, Marian,Richmond, Edward,Li, Guang,Moran, Joseph
, p. 45 - 51 (2016/12/06)
A B(C6F5)3[rad]H2O-catalyzed defluorinative functionalization of tertiary aliphatic fluorides is described that proceeds under benign reaction conditions. The synthetic utility of the method is exemplified throu
Alkylation of dicarbonyl compounds with 1-bromoadamantane in the presence of metal complex catalysts
Khusnutdinov,Shchadneva,Khisamova
, p. 329 - 331 (2016/06/06)
Adamantyl-substituted dicarbonyl compounds have been synthesized by reactions of 1-bromo-adamantane with ethyl acetoacetate, 1,3-diphenylpropane-1,3-dione, and dimethyl malonate in the presence of iron and manganese complexes.
Adamantylation of β-dicarbonyl compounds
Turmasova,Spesivaya,Konshina, Dzh. N.,Konshin
, p. 1733 - 1735 (2013/11/19)
Reactions of adamantan-1-ol with β-dicarbonyl compounds in 1,2-dichloroethane in the presence of In(OTf)3, Ga(OTf)3, Sc(OTf)3, or Cu(OTf)2 give the corresponding adamantylated derivatives in 45-93% yields.
METAL COMPLEXES IN ORGANIC SYNTHESIS. PREPARATION OF α-(1-ADAMANTYL)-β-DICARBONYL COMPOUNDS AND 4-(1-ADAMANTYL)-3,5-DISUBSTITUTED PYRAZOLES AND ISOXAZOLES.
Gonzalez, A.,Marquet, J.,Moreno-Manas, M.
, p. 4253 - 4258 (2007/10/02)
α-(1-adamantyl)-β-dicarbonyl compounds are prepared by the reactions of the Co(II) complexes of β-dicarbonyl compounds with 1-bromoadamantane.This provides a route to the previously inaccessible 4-(1-adamantyl)-3,5-disubstituted pyrazoles and isoxazoles.
ALKYLATION OF β-DIKETONES THROUGH THEIR Co(II), Co(III) AND Zn(II) COMPLEXES. 1-BROMOADAMANTANE AS ALKYLATING AGENT.
Gonzalez, A.,Gueell, F.,Marquet, J.,Moreno-Manas, M.
, p. 3735 - 3738 (2007/10/02)
α-(1-Adamantyl)-β-diketones are now accessible by the alkylation of Co(II) complexes of β-diketones with 1-bromoadamantane.The intermediacy of adamantyl cation is proposed.Co(II), Co(III) and Zn(II) complexes of pentane-2,4-dione react with alkyl halides precursors of stabilized carbenium ions, to give 3-alkylpentane-2,4-diones.
