1024586-02-4Relevant academic research and scientific papers
Palladium-catalyzed direct ortho C-H arylation of 2-arylpyridine derivatives with aryltrimethoxysilane
Li, Wu,Yin, Zhangwei,Jiang, Xiaoqing,Sun, Peipei
experimental part, p. 8543 - 8548 (2011/12/03)
A Pd(OAc)2-catalyzed cross-coupling reaction between 2-arylpyridine and aryltrimethoxysilane in the presence of AgF and BQ in 1,4-dioxane was studied. After various reaction parameters (catalyst, oxidant, additive, solvent and reaction temperat
Iron-catalyzed direct arylation through directed C-H bond activation
Norinder, Jakob,Matsumoto, Arimasa,Yoshikai, Naohiko,Nakamura, Eiichi
, p. 5858 - 5859 (2008/09/19)
An iron-catalyzed C-C bond formation reaction of a nitrogen-containing aromatic compound with an arylzinc reagent takes place at 0 °C in a good to quantitative yield. The reaction involves a C-H bond activation directed by a neighboring nitrogen atom. The important additives in this reaction are 1,10-phenanthroline, tetramethylethylenediamine, and 1,2-dichloro-2-methylpropane, in the absence of which a very low product yield was observed. Copyright
