1024598-13-7Relevant academic research and scientific papers
Intramolecular Friedel-Crafts type reaction of vinyloxiranes linked to an ester group
Nagumo, Shinji,Miura, Toshie,Mizukami, Megumi,Miyoshi, Irie,Imai, Masanori,Kawahara, Norio,Akita, Hiroyuki
experimental part, p. 9884 - 9896 (2010/01/16)
The 7-endo Friedel-Crafts cyclization of arylpropyl vinyloxiranes was found to proceed regio- and stereoselectively to afford polyfunctional seven-membered carbocycles in excellent yields.
Hg(OTf)2-catalyzed arylene cyclization
Namba, Kosuke,Yamamoto, Hirofumi,Sasaki, Ikuo,Mori, Kumiko,Imagawa, Hiroshi,Nishizawa, Muaio
supporting information; experimental part, p. 1767 - 1770 (2009/04/12)
Novel Hg(OTf)2-catalyzed arylene cyclization was achieved with highly efficient catalytic turnover (up to 200 times). The reaction takes place via protonation of allylic hydroxyl group by in situ formed TfOH of an organomercurlc intermediate to
