102493-56-1

Basic information

• Product Name: 4-<1,2-bis(4-methoxyphenyl)ethyl>-1-naphthalenecarbonitrile
• Synonyms: 4-<1,2-bis(4-methoxyphenyl)ethyl>-1-naphthalenecarbonitrile
• CAS NO: 102493-56-1
• Molecular Weight: 393.485
• Mol File: 102493-56-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-<1,2-bis(4-methoxyphenyl)ethyl>-1-naphthalenecarbonitrile(CAS DataBase Reference)
• NIST Chemistry Reference: 4-<1,2-bis(4-methoxyphenyl)ethyl>-1-naphthalenecarbonitrile(102493-56-1)
• EPA Substance Registry System: 4-<1,2-bis(4-methoxyphenyl)ethyl>-1-naphthalenecarbonitrile(102493-56-1)

Safety Data

• Hazardous Substances Data: 102493-56-1(Hazardous Substances Data)

Upstream product

• 3029-30-9 naphthalene-1,4-dicarbonitrile 
• 1657-55-2 1,2-bis(4-methoxyphenyl)ethane 

Relevant articles and documents

Photochemical Reaction of 1,4-Naphthalenedicarbonitrile with Alkylbenzenes and Bibenzyls

The photochemical reaction of 1,4-naphthalenedicarbonitrile with some alkylbenzenes and bibenzyls has been examined.A unitary mechanistic picture is formulated on the basis of product study, deuteration experiments, and fluorescence and reaction quantum yield measurements.Proton transfer within the singlet radical ion pair followed by in-cage cycloaddition of the two radicals yields stereoselectively 5,11-methanodibenzo cyclooctene derivatives (8).Reaction of benzyl radicals (formed by protolysis or, for radical cations having no benzylic proton, by C-C bond cleavage) with unprotonated NDN.- leads, again stereoselectively, to 2-benzyl-1,2-dihydronaphtalenes (9).Escape of the donor radical cation and following C-H or C-C bond cleavage leads to a different product, thus, benzyl radicals are trapped by NDN to yield substitution products (11) or recombine.Benzyl cations are trapped by nucleophiles.